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A b. PSfrag replacements a a b c γ b γ c. PSfrag replacements PSfrag replacements a b c a b c d. PSfrag replacements a b c e. f. c Figure 16: Bravais cells for orthotropic symmetry. (a) Primitive unit-cell with standard orthotropic metric. Unit-cells (b), (d) and (f) are not used to describe the structure of space grids. The non-primitive (c) C-, (e) I- and (g) F-centered cells are used instead. 4. Tetragonal Symmetry Up to this point, the introduced symmetry operations only affected the angles of the unit-cells, not the ratio of the edges.

Jagodzinski [57], Voigt [142], Borchardt-Ott [24] or Kleber, Bautsch & Bohm [61]. For the approach presented here we refer especially to the books of Whittaker [152] and Kennon [60]. A comprehensive work is the “International Tables for Crystallography” edited by Hahn [45]. For an introduction to the group theoretical treatment of symmetry we refer to Hamermesh [47] among many others. Condensed matter is distinguished between solids having amorphous and those having crystalline microstructure. We focus here on the latter ones.

Balance of Entropy and Second Law of Thermodynamics Entropy is a state variable for a thermo-mechanical system which measures microscopic randomness and disorder and determines the direction of the thermodynamical process.. Its physical definition is part of Statistical Physics. The entropy H possessed by a part of a body is defined in terms of the specific entropy per unit mass η as ρ0 η dV . 59) Bp A temporal change of the entropy of a body can be caused by (i ) a production of entropy ργ, (ii ) a source of entropy inside the body ρr/θ due to evolution of temperature and (iii ) a supply of entropy through the surface due to heat flux −q · n/θ.